Hello everyone,
I calculated the cohesive energy density of two atomic systems(Poly4-vinylpyridine(P4VP) and Poly2-vinylpyridine(P2VP)).
Poly4-vinylpyridine(P4VP) Poly2-vinylpyridine(P2VP)
The two systems have one chain including twenty P4VP and P2VP monomers.
I found inter energy of the two systems are little different but total energy and intra energy of the two systems are quite different.
I would like to know what cause the difference of energy.
Best regards,
Martin