Interactions of a guest metal complex and a host polymer

On guest-host chemistry. What would be the most reasonable way to study the binding interactions (mostly electrostatic) between a metal complex and a polymer matrix? Since the complex is photoactive, we'r interested in the photophysical properties of the complex and the effect of the polymer on these properties. And how to study the UV-Vis absorption and redox properties of the complex in the polymer matrix? Thanks a lot.